Can I have a different Gmail than the one associated with my Android account?

I do not use the Gmail address associated with my Android account for my Note 3, Android Version 5.0 (which AT&T claims is up to date), because it receives too many emails (things that can sit there until I'm home and open up on my PC). I would like to open a new Gmail account to replace my Yahoo email. Is it possible to use a second Gmail edress (but not the first one) for my Android phone?

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